Calcium carbonate

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Infobox on Calcium carbonate
Example of Calcium carbonate
Calcium carbonate.jpg
Facts
Origin -
Stowage factor (in m3/t) 1,78 m3/t (kegs) (Chalk limestone)
1,34 m3/t (bags) preciptated
Humidity / moisture -
Ventilation -
Risk factors See text

Calcium carbonate

Description

Calcium carbonate is a chemical compound with the formula CaCO3. It is a common substance found in rocks in all parts of the world, and is the main component of shells of marine organisms, snails, coal balls, pearls, and eggshells. Calcium carbonate is the active ingredient in agricultural lime, and is created when Ca ions in hard water reacts with carbonate ions creating limescale.

The vast majority of calcium carbonate used in the industry is extracted by mining or quarrying. Pure calcium carbonate (e.g. for food or pharmaceutical use), can be produced from a pure quarried source (usually marble).

Alternatively, calcium carbonate is prepared from calcium oxide. Water is added to create calcium hydroxide, and carbon dioxide is passed through this solution to precipitate the desired calcium carbonate, referred to in the industry as precipitated calcium carbonate (PCC).

Calcium carbonate; a white powder or colourless crystals, tasteless, decomposes at 825°C, non combustible, very slightly soluble in water (a few ppm), soluble in acids with evolution of carbon dioxide.

Application

Source of lime; neutralizing agent, filler and extender in rubber, plastics, paints; opacifying agent in paper; fortification of bread; putty, tooth powders; antacid; whitewash; Portland cement; sulfur dioxide removal from stack gases; metallurgical flux; analytical chemistry; carbon dioxide generation (laboratory).

Calcium carbonate is a major cause of boiler scale when hard water is used in heating systems.

Shipment / Storage

Calcium carbonate is not listed as a dangerous cargo.

For safe handling consult the applicable MSDS sheet.

Risk factors

Hazard: a nuisance particulate dust. TLV: 5 mg/m3 of air.