Difference between revisions of "Salt"

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==Description==
 
==Description==
"Salt" is the colloquial term for the chemical compound sodium chloride (NaCl). It is principally obtained by four processes:<br><br>
+
Salt, also known as table salt, or rock salt, is a crystalline mineral that is composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of ionic salts. It is essential for animal life in small quantities, but is harmful to [[animals]] and [[plants]] in excess. Salt is one of the oldest, most ubiquitous food seasonings and salting is an important method of food preservation. The taste of salt (saltiness) is one of the basic human tastes.<br><br>
* by mining of rock salt. In Germany, approx. 90% of all NaCl is obtained in this way.
+
Salt for human consumption is produced in different forms: unrefined salt (such as sea salt), refined salt (table salt), and iodized salt. It is a crystalline solid, white, pale pink or light gray in color, normally obtained from sea water or rock deposits. Edible rock salts may be slightly grayish in color because of mineral content.<br><br>
* by the evaporation of natural or artificial saturated aqueous NaCl solutions. This may proceed with the aid of brines, which are obtained by pumping water into underground salt beds or from salt works ("boiled salt").
+
Chloride and sodium ions, the two major components of salt, are needed by all known living creatures in small quantities. Salt is involved in regulating the water content (fluid balance) of the body. The sodium ion itself is used for electrical signaling in the nervous system. Because of its importance to survival, salt has often been considered a valuable commodity during human history. However, as salt consumption has increased during modern times, scientists have become aware of the health risks associated with too much salt intake, including high blood pressure. Therefore health authorities have recommended limitations of dietary sodium.<br><br>
* by evaporation of saline seawater collected in large ponds or of water from salt lakes in hot countries (such as Spain or Southern France). This salt is also called sea salt.
+
Different natural salts have different mineralities, giving each one a unique flavor. Fleur de sel, a natural sea salt from the surface of evaporating [[brine]] in salt pans, has a unique flavor varying from region to region. Completely raw sea salt is bitter because of magnesium and calcium compounds, and thus is rarely eaten. Unrefined sea salts are also commonly used as ingredients in bathing additives and cosmetic products. <br><br>
* as a by-product of seawater desalination for obtaining drinking or process water.<br><br>
+
Food grade salt accounts for only a small part of salt production in industrialized countries  although worldwide, food uses account for 17.5 percent of salt production. The majority is sold for industrial use. Salt has great commercial value because it is a necessary ingredient in many manufacturing processes. A few common examples include: the production of pulp and paper, setting dyes in textiles and fabrics, and the making of soaps and detergents.<br><br>
Salt has a solid, crystalline structure and is very hygroscopic. It attacks metals when combined with moisture.<br><br>
+
The manufacture and use of salt is one of the oldest chemical industries. Salt can be obtained by evaporation of sea water, usually in shallow basins warmed by sunlight; salt so obtained was formerly called bay salt, and is now often called sea salt or solar salt. Rock salt deposits are formed by the evaporation of ancient salt lakes, and may be mined conventionally or through the injection of water. Injected water dissolves the salt, and the brine solution can be pumped to the surface where the salt is collected.<br><br>
 +
Table salt is refined salt, which contains about 97 to 99 percent sodium chloride. It usually contains substances that make it free-flowing (ant-caking agents) such as sodium silicoaluminate or [[Magnesium Carbonate]]. <br><br>
 +
Most table salt sold for consumption contains a variety of additives, which address a variety of health concerns, especially in the developing world. The amounts of additives vary widely from country to country.<br><br>
  
 
==Applications==
 
==Applications==
Salt is used, among other things, as:<br><br>
+
Salt is produced by evaporation of seawater or [[brine]] from other sources, such as brine wells and salt lakes, and by mining rock salt, called halite.
* cooking salt or table salt, as a seasoning for human consumption,
+
Apart from its use in table salt in the diet, sodium chloride is a major industrial chemical. It occurs widely, being the main saline component of the oceans, and plays a role in formation of clouds.<br><br>
* curing salt, for salt meat and fish,
+
==Shipment / storage / usage==
* cattle lick (dyed with [[iron oxide]]) in animal husbandry.
+
When stowed in containers a high standard of container preparation is required, ensuring the interior of the container is absolutely dry and clean. It is important the bags are of good quality and not stowed with goods that might emit moisture. As protection for the container, it is recommended that an innerliner is fitted.<br><br>
* industrial salt for freezing mixtures (denatured with kerosene or marked with dyes),
+
Salt corrodes steelwork, therefore for breakbulk shipments all steel structures in the holds are given two coats of whitewash. Cracks in ceilings and planking must be effectively stopped up. Salt is not to be loaded together with cargoes emitting/attracting moisture. During the voyage, salt may loose 5% in weight by evaporation.
* salt grit for clearing roads in winter,
+
A bulk liner bag is fitted inside the container and the cargo can be either blown into a zip up bag or brought in by bob cat shovel to an enveloping liner bag. In both cases a door bulkhead must be created and this can be done either by bars fitted into the doorway recess  or by bagging a portion of the cargo to hold the liner in position across the doorway.<br><br>
* pit salt for combatting [[coal]] dust in mining,
+
Common salt is shipped in bags or in bulk. Subject to loss of weight due to evaporation. On a long voyage this may be 5% or more. When shipped in jute bags contact with iron results in rusting of the metal, which stains and rusts the bags, with subsequent bursting on handling and loss of contents. Should sacks be repaired, careful attention should be paid to the re-sewn portions, as this loss might be confused with loss due to ‘normal tearing’. The salt nearest to the torn portion of the bag is usually rust stained. Damaged salt, if unfit for the purpose of which it was intended, may attract a reasonable figure for agricultural purposes. With bulk cargoes holds should be limewashed before loading.<br><br>
* hide salt for curing hides.<br><br>
+
If allowed to absorb too much water vapor, salt begins to flow. If the water vapor is released again, lumps form. Depending on its intended use, care should be taken to ensure that salt remains pourable and does not tend towards lump formation. This may be achieved by adding appropriate additives (anti-caking agents). If salt is stored in suitably dry and warm conditions, it may be stored for several years. <br><br>
 
 
==Storage/Transport==
 
If allowed to absorb too much water vapor, salt begins to flow. If the water vapor is released again, lumps form. Depending on its intended use (e.g. cooking salt), care should be taken to ensure that salt remains pourable and does not tend towards lump formation. This may be achieved by adding appropriate additives. Salt producers therefore use sodium ferrocyanide, which prevents salt crystals from agglomerating (sticking together).
 
<br><br>
 
If salt is stored in suitably dry and warm conditions, it may be stored for several years. Salt is transported as bulk cargo as well as in barrels and bags (e.g. 3 - 5-ply paper bags with single plastic lining, 50 kg). The plastic lining prevents water vapor exchange between product and hold or container air. Smaller amounts may also be packaged in cartons or cans ready for retail sale.
 
<br><br>
 
Standard containers and bulk containers may be used, subject to compliance with lower limits for water content of goods, packaging and container flooring. In damp weather (rain, snow), the cargo must be protected from moisture. Stow dry. Because of their impact- and pressure-sensitivity, the packaging containers must be secured in such a way that damage is prevented. Bags must not develop tears and barrels must not break apart. Spaces between packages or pallets must be filled, to prevent slippage or tipping. Pallets must be loaded flush with their edges as protruding packages may readily result in damage.
 
<br><br>
 
<b>Temperature</b><br>
 
Favorable travel temperature range: no lower limit - 25°C. If salt is transported into the subtropics and tropics, the temperature of the cargo of salt on unloading in the port of destination must be higher than the dew point temperature of the outside air, so as to prevent sweat from forming on the cargo.
 
<br><br>
 
If salt is loaded in Europe in the winter months, the consignor should ensure that the temperature of the salt is not below freezing point, as it is difficult to heat the product up during the voyage to tropical ports of destination. The most favorable cargo temperature is 15 - 20°C. Such salt (even in containers) may be stowed in the lower holds, as there is sufficient time for slow heating of the cargo given the relatively slight temperature difference between the port of loading and the port of discharge. However, if the temperature of the salt at the port of loading is 0 - 10°C, it should preferably be stowed in holds above the water line, so as to achieve faster heating of the cargo.<br><br>
 
{|
 
|-
 
|style="width:250px;"|<b>Designation</b>
 
|style="width:150px;"|<b>Humidity/water content</b>
 
|-
 
| Relative Humidity
 
| 55 - 65%
 
|-
 
| Water content
 
| 0.05 - 0.5%
 
|-
 
| Maximum equilibrium moisture content
 
| 65%
 
|-
 
|}<br>
 
 
 
At up to 74% relative humidity and 20°C, salt does not absorb any appreciable quantities of water vapor. The critical water content of sodium chloride (NaCl) is 0.5% at 74% relative humidity, which is the flow moisture point at which salt begins readily to absorb water vapor, and increases such that, at 75% relative humidity, the salt dissolves (hygroscopicity). If salt is loaded as bulk cargo, it is at risk from direct exposure to moisture, such as rain, snow or condensation water, during both cargo handling and transport.
 
<br><br>
 
The water vapor absorption of the salt is particularly critical when its temperature is below the dew point temperature of the hold or container air (see RF Temperature). In this case, the condensation zone spreads throughout the entire cargo and the salt becomes thoroughly wet. It is not possible to dry the wettened cargo of salt by ventilation, as it hardens and cakes when it releases water vapor due to recrystallization, so leaving monolithic surfaces. The utility value of the product is reduced considerably by the loss of flowability and the unloading process is rendered more difficult.
 
<br><br>
 
Hygroscopicity is increased by the addition of companion salts, such as KCl and MgCl2. If the product is packaged in paper bags with plastic linings, a higher relative humidity than that indicated above is feasible. However, a higher relative humidity makes the paper packaging damp, so that it may be damaged during cargo handling.
 
<br><br>
 
<b>Ventilation</b><br>
 
Salt requires particular humidity/moisture and possibly ventilated conditions. As bagged salt is protected from water vapor exchange by a plastic lining, it does not normally need to be ventilated. However, if it is transported as bulk cargo, note should be taken of the behavior of a cargo block in the event of temperature changes:<br><br>
 
* transport from temperate latitudes to the tropics = travel from cold to hot: the cargo block is heated from the outside, resulting in water vapor transport from the outside to the cold core, which causes caking of the outer layers while the inner layers display wetting phenomena (syrup formation).<br><br>
 
* transport from the tropics to temperate latitudes = travel from hot to cold: if the cargo block cools down from the outside, resulting in water vapor transport from the warm core to the outside, wetness and mold may occur there while inside the release of water vapor by the warm core results in caking phenomena (loss of flowability).<br><br>
 
<b>Biotic activity</b><br>
 
Salt displays zero order biotic activity. Salt is a nonliving product and does not therefore display any biotic activity.
 
<br><br>
 
<b>Gases</b><br>
 
Salt does not normally evolve any gases. However, [[contact]] with [[acids]] leads to the liberation of chlorine, which has an asphyxiating action and is toxic.
 
<br><br>
 
  
 
==Risk factors==
 
==Risk factors==
<b>Self-heating / Spontaneous combustion</b><br>
+
* Odor
No risk.
+
* Moisture
<br><br>
+
* Contamination
<b>Odor</b><br>
+
* Mechanical influences
<i>Active behavior:</i> Salt does not release any odor.<br>
+
* Toxicity / Hazards to health
<i>Passive behavior:</i> Salt is sensitive to unpleasant or pungent odors. It must not be loaded in holds or containers which were previously used to transport living [[animals]] or other odor-tainting goods. To prevent spoilage of salt, it must not be stored together with sugar, hides, tobacco, fish products and other goods with an intense odor.
+
* Shrinkage/Shortage
<br><br>
 
<b>Contamination</b><br>
 
<i>Active behavior:</i> Salt creates dust. Goods at risk of rusting, such as iron, sheet metal, wire coils, engines, machinery or motor vehicles, may be rapidly corroded by salt dust in conjunction with moisture.<br>
 
<i>Passive behavior</i> Salt is sensitive to dust, dirt, fats and oils. The holds or containers must accordingly be clean and in a thoroughly hygienic condition before loading.
 
<br><br>
 
If the product is transported in linen cloth bags, anyone entering the holds or containers must do so only in soft, clean footwear, as salt is very sensitive to contamination. Salt solutions and salt dust have a highly corrosive action on metals.
 
<br><br>
 
<b>Mechanical influences</b><br>
 
Because of the impact- and pressure-sensitivity of the bags and barrels, they must be handled with appropriate care during cargo handling, transport and storage. No hooks of any kind may be used during handling of bagged goods, as they cause the salt to trickle out of the bags. Where plastic packaging is damaged, humidity and temperature fluctuations may lead to agglomeration, so rendering the surface monolithic (particularly in the case of fine-grained salt).
 
<br><br>
 
<b>Toxicity / Hazards to health</b><br>
 
There is normally no risk. Storage together with [[acids]] results in the formation of chlorine, which is asphyxiating and toxic.
 
<br><br>
 
<b>Shrinkage/Shortage</b><br>
 
Weight losses of approx. 5% due to water vapor release are deemed normal. To these must be added trickle losses, which arise during cargo handling.
 
<br><br>
 
 
 
==Additional information==
 
When stowed in containers a high standard of container preparation is required, ensuring the interior of the container is absolutely dry and clean. It is important the bags are of good quality and not stowed with goods that might emit moisture. As protection for the container, it is recommended that an innerliner is fitted.
 
<br><br>
 
Salt corrodes steelwork, therefore for breakbulk shipments all steel structures in the holds are given two coats of whitewash. Cracks in ceilings and planking must be effectively stopped up. Salt is not to be loaded together with cargoes emitting/attracting moisture. During the voyage, salt may loose 5% in weight by evaporation. A bulk liner bag is fitted inside the container and the cargo can be either blown into a zip up bag or brought in by bob cat shovel to an enveloping liner bag. In both cases a door bulkhead must be created and this can be done either by bars fitted into the doorway recess  or by bagging a portion of the cargo to hold the liner in position across the doorway.
 
<br><br>
 
Common salt is shipped in bags or in bulk. Subject to loss of weight due to evaporation. On a long voyage this may be 5% or more. When shipped in jute bags [[contact]] with iron results in rusting of the metal, which stains and usts the bags, with subsequent bursting on handling and loss of contents. Should sacks be repaired, careful attention should be paid to the re-sewn portions, as this loss might be confused with loss due to ‘normal tearing’. The salt nearest to the torn portion of the bag is usually rust stained. Damaged salt, if unfit for the purpose of which it was intended, may attract a reasonable figure for agricultural purposes. With bulk cargoes holds should be limewashed before loading.
 
<br><br>
 
Note:<i>(Source including Transport Information Service of the GDV)</i>
 
 
 
  
 
[[Category: Products]]
 
[[Category: Products]]
 
[[Category: Food and beverages]]
 
[[Category: Food and beverages]]

Latest revision as of 10:50, 18 January 2021

Infobox on Salt
Example of Salt
Salt.jpg
Facts
Origin Salt is produced extensively over all continents.
Stowage factor (in m3/t)
  • 1.25 m3/t (paper bags, 5-ply with plastic lining, 50 kg)
  • 1.47 m3/t (wooden barrels)
  • 1.06 - 1.11 m3/t (bags)
  • 0.98 - 1.11 m3/t (bulk)
Humidity / moisture
  • Relative humidity: 55 - 65%
  • Water content 0.05 - 0.5%
  • Maximum equilibrium moisture content: 65%
Oil content -
Ventilation Salt requires particular humidity/moisture and possibly ventilation conditions (storage climate conditions).

As bagged salt is protected from water vapor exchange by a plastic lining, it does not normally need to be ventilated.

However, if it is transported as bulk cargo, note should be taken of the behavior of a cargo block in the event of temperature changes:

* transport from temperate latitudes to the tropics = travel from cold to hot: the cargo block is heated from the outside, resulting in water vapor transport from the outside to the cold core, which causes caking of the outer layers while the inner layers display wetting phenomena (syrup formation).

* transport from the tropics to temperate latitudes = travel from hot to cold: if the cargo block cools down from the outside, resulting in water vapor transport from the warm core to the outside, wetness and mold may occur there while inside the release of water vapor by the warm core results in caking phenomena (loss of flowability).
Risk factors Salt is sensitive to unpleasant or pungent odors.

Salt is sensitive to contamination and moisture damage.
Salt solutions and salt dust have a highly corrosive action on metals.

Weight losses of approx. 5% due to water vapor release are deemed normal. To these must be added trickle losses, which arise during cargo handling.

Salt

Description

Salt, also known as table salt, or rock salt, is a crystalline mineral that is composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of ionic salts. It is essential for animal life in small quantities, but is harmful to animals and plants in excess. Salt is one of the oldest, most ubiquitous food seasonings and salting is an important method of food preservation. The taste of salt (saltiness) is one of the basic human tastes.

Salt for human consumption is produced in different forms: unrefined salt (such as sea salt), refined salt (table salt), and iodized salt. It is a crystalline solid, white, pale pink or light gray in color, normally obtained from sea water or rock deposits. Edible rock salts may be slightly grayish in color because of mineral content.

Chloride and sodium ions, the two major components of salt, are needed by all known living creatures in small quantities. Salt is involved in regulating the water content (fluid balance) of the body. The sodium ion itself is used for electrical signaling in the nervous system. Because of its importance to survival, salt has often been considered a valuable commodity during human history. However, as salt consumption has increased during modern times, scientists have become aware of the health risks associated with too much salt intake, including high blood pressure. Therefore health authorities have recommended limitations of dietary sodium.

Different natural salts have different mineralities, giving each one a unique flavor. Fleur de sel, a natural sea salt from the surface of evaporating brine in salt pans, has a unique flavor varying from region to region. Completely raw sea salt is bitter because of magnesium and calcium compounds, and thus is rarely eaten. Unrefined sea salts are also commonly used as ingredients in bathing additives and cosmetic products.

Food grade salt accounts for only a small part of salt production in industrialized countries although worldwide, food uses account for 17.5 percent of salt production. The majority is sold for industrial use. Salt has great commercial value because it is a necessary ingredient in many manufacturing processes. A few common examples include: the production of pulp and paper, setting dyes in textiles and fabrics, and the making of soaps and detergents.

The manufacture and use of salt is one of the oldest chemical industries. Salt can be obtained by evaporation of sea water, usually in shallow basins warmed by sunlight; salt so obtained was formerly called bay salt, and is now often called sea salt or solar salt. Rock salt deposits are formed by the evaporation of ancient salt lakes, and may be mined conventionally or through the injection of water. Injected water dissolves the salt, and the brine solution can be pumped to the surface where the salt is collected.

Table salt is refined salt, which contains about 97 to 99 percent sodium chloride. It usually contains substances that make it free-flowing (ant-caking agents) such as sodium silicoaluminate or Magnesium Carbonate.

Most table salt sold for consumption contains a variety of additives, which address a variety of health concerns, especially in the developing world. The amounts of additives vary widely from country to country.

Applications

Salt is produced by evaporation of seawater or brine from other sources, such as brine wells and salt lakes, and by mining rock salt, called halite. Apart from its use in table salt in the diet, sodium chloride is a major industrial chemical. It occurs widely, being the main saline component of the oceans, and plays a role in formation of clouds.

Shipment / storage / usage

When stowed in containers a high standard of container preparation is required, ensuring the interior of the container is absolutely dry and clean. It is important the bags are of good quality and not stowed with goods that might emit moisture. As protection for the container, it is recommended that an innerliner is fitted.

Salt corrodes steelwork, therefore for breakbulk shipments all steel structures in the holds are given two coats of whitewash. Cracks in ceilings and planking must be effectively stopped up. Salt is not to be loaded together with cargoes emitting/attracting moisture. During the voyage, salt may loose 5% in weight by evaporation. A bulk liner bag is fitted inside the container and the cargo can be either blown into a zip up bag or brought in by bob cat shovel to an enveloping liner bag. In both cases a door bulkhead must be created and this can be done either by bars fitted into the doorway recess or by bagging a portion of the cargo to hold the liner in position across the doorway.

Common salt is shipped in bags or in bulk. Subject to loss of weight due to evaporation. On a long voyage this may be 5% or more. When shipped in jute bags contact with iron results in rusting of the metal, which stains and rusts the bags, with subsequent bursting on handling and loss of contents. Should sacks be repaired, careful attention should be paid to the re-sewn portions, as this loss might be confused with loss due to ‘normal tearing’. The salt nearest to the torn portion of the bag is usually rust stained. Damaged salt, if unfit for the purpose of which it was intended, may attract a reasonable figure for agricultural purposes. With bulk cargoes holds should be limewashed before loading.

If allowed to absorb too much water vapor, salt begins to flow. If the water vapor is released again, lumps form. Depending on its intended use, care should be taken to ensure that salt remains pourable and does not tend towards lump formation. This may be achieved by adding appropriate additives (anti-caking agents). If salt is stored in suitably dry and warm conditions, it may be stored for several years.

Risk factors

  • Odor
  • Moisture
  • Contamination
  • Mechanical influences
  • Toxicity / Hazards to health
  • Shrinkage/Shortage