Clays
| Infobox on Clays | |
|---|---|
| Example of Clays |  |
| Facts | |
| Origin |
|
| Stowage factor (in m3/t) |
|
| Humidity / moisture | Moisture up to 25% |
| Ventilation | No special requirements |
| Risk factors | See text |
Clays
Description / Application
Clay is a naturally occurring Aluminium Silicate composed primarily of fine-grained minerals. Clay deposits are mostly composed of clay minerals, a subtype of phyllosilicate minerals, which impart plasticity and harden when fired or dried; they also may contain variable amounts of water trapped in the mineral structure by polar attraction. Organic materials which do not impart plasticity may also be a part of clay deposits.
Clay minerals are typically formed over long periods of time by the gradual chemical weathering of rocks, usually silicate-bearing, by low concentrations of carbonic acid and other diluted solvents. These solvents, usually acidic, migrate through the weathering rock after leaching through upper weathered layers. In addition to the weathering process, some clay minerals are formed by hydrothermal activity. Clay deposits may be formed in place as residual deposits in soil, but thick deposits usually are formed as the result of a secondary sedimentary deposition process after they have been eroded and transported from their original location of formation. Clay deposits are typically associated with very low energy depositional environments such as large lakes and marine deposits.
Primary clays, also known as kaolins, are located at the site of formation. Secondary clay deposits have been moved by erosion and water from their primary location.
Clays are distinguished from other fine-grained soils by differences in size and mineralogy. Silts, which are fine-grained soils that do not include clay minerals, tend to have larger particle sizes than clays, but there is some overlap in both particle size and other physical properties, and there are many naturally occurring deposits which include both silts and clays. The distinction between silt and clay varies by discipline. Geologists and soil scientists usually consider the separation to occur at a particle size of 2 µm (clays being finer than silts), sedimentologists often use 4-5 μm, and colloid chemists use 1 μm. Geotechnical engineers distinguish between silts and clays based on the plasticity properties of the soil, as measured by the soils' Atterberg Limits. ISO 14688 grades clay particles as being smaller than 2 μm and silts larger.
Depending on the academic source, there are three or four main groups of clays: kaolinite, montmorillonite-smectite, illite, and chlorite. Chlorites are not always considered a clay, sometimes being classified as a separate group within the phyllosilicates. There are approximately 30 different types of "pure" clays in these categories, but most "natural" clays are mixtures of these different types, along with other weathered minerals.
Varve (or varved clay) is clay with visible annual layers, formed by seasonal differences in erosion and organic content. This type of deposit is common in former glacial lakes. When glacial lakes are formed there is very little movement of the water that makes the lake, and these eroded soils settle on the lake bed. This allows such an even distribution on the different layers of clay.
Quick clay is a unique type of marine clay indigenous to the glaciated terrains of Norway, Canada, Northern Ireland, and Sweden. It is a highly sensitive clay, prone to liquefaction, which has been involved in several deadly landslides.
Dry clay is normally much more stable than sand with regard to excavations.
Clays exhibit plasticity when mixed with water in certain proportions. When dry, clay becomes firm and when fired in a kiln, permanent physical and chemical changes occur. These reactions, among other changes, cause the clay to be converted into a ceramic material. Because of these properties, clay is used for making pottery items, both utilitarian and decorative. Different types of clay, when used with different minerals and firing conditions, are used to produce earthenware, stoneware, and porcelain. Depending on the content of the soil, clay can appear in various colors, from a dull gray to a deep orange-red.
Clays sintered in fire were the first form of ceramic. Bricks, cooking pots, art objects, dishware, and even musical instruments such as the ocarina can all be shaped from clay before being fired. Clay is also used in many industrial processes, such as paper making, cement production, and chemical filtering. Clay is also often used in the manufacture of pipes for smoking tobacco. Until the late 20th century bentonite clay was widely used as a mold binder in the manufacture of sand castings.
Clay, being relatively impermeable to water, is also used where natural seals are needed, such as in the cores of dams, or as a barrier in landfills against toxic seepage (lining the landfill, preferably in combination with geotextiles).
Recent studies have investigated clay's absorption capacities in various applications, such as the removal of heavy metals from waste water and air purification.
Clay is one of the oldest building materials on Earth, among other ancient, naturally-occurring geologic materials such as stone and organic materials like wood. Between one-half and two-thirds of the world's population, in traditional societies as well as developed countries, still lives or works in a building made with clay as an essential part of its load-bearing structure. Also a primary ingredient in many natural building techniques, clay is used to create adobe, cob, cordwood, and rammed earth structures.
Use; ceramic products, refractories, colloidal suspensions, oil-well drilling fluids, filler for rubber and plastic products, films, paper coating, decolorizing oils, temporary molds, filtration, carrier in insecticidal sprays, catalyst support.
Shipment / Storage
Clay is usually light to dark grey and comprises 10% soft lumps and 90% soft grains. The material is usually shipped in bulk; is moist but not wet to the touch.
This cargo shall be kept as dry as practicable and should not be handled during precipitation. The moisture content of this cargo shall be kept as low as practicable to prevent the cargo becoming glutinous and handling of the cargo becoming extremely difficult.
See IMSBC Code.
Risk factors
Dusts may be irritant to nose and throat. Suspensions of dust are a fire hazard.